Web Access Research Portal

Researcher: Jin, H (Dr Hong Jin)

Fields of Research

Organometallic chemistry
Transition metal chemistry

Research Objectives

Expanding knowledge in the chemical sciences

Career Best Publications

Research Publications

Allenyl-propargyl tautomerism at palladium(IV) and platinum(IV) centres; Journal of Organometallic Chemistry
Coordination geometries for palladium and platinum: theoretical studies and the synthesis and structure of tris(indazol-l-y) borate complexes MMe3{(ind)3BH}; Inorganica Chimica Acta
Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes; Inorganic Syntheses
Group 16 oxidants (O2CPh)2, (SPh)2 and (SePh)2: synthesis of Pd(IV) and Pt(IV) complexes and CO, CS, and CSe bond formation at Pd(IV); RACI, Inorganic Chemistry Division Confernece, IC'98
Hydrogen-bonding 'Pd(OH)...2(HOAr)' and '[Pd(OH2)+...-OAr]²2', and protonation of a hydroxo-ligand by pentafluorophenol in organopalladium(IV) chemistry. Structural studies of the pallada(IV)cyclopentane adducts [Pd(OH)(C4H8){(pz)3BH}.2(3-MeC6H4OH)] and [; Journal of Organometallic Chemistry
Hydrogen-bonding in organopalladium(IV) complexes: Pd(OH)...HOAr and Pd(OH2)+ ... -OAr interactions; 213th American Chemical Society National Meeting
Insertion into the nickel-carbon bond of N-O chelated arylnickel(II) complexes. The development of single component catalysts for the oligomerisation of ethylene; Journal of Organometallic Chemistry
Mechanistic Aspects of CO and ethylene insertion. Isolation of an important intermediate from the catalytic formation of polyketones; XVIIth International Conference of Organometallic Chemistry
Organopalladium(IV) Complexes containing hydroxo ligands hydrogen-bonded to aryl alcohols and an aqua ligand hydrogen-bonded to pentafluorophenoxide; XVIIth International Conference on Organometallic Chemistry
Oxidation of complexes by (O2CPh)(2) and (ER)(2) (E = S, Se), including structures of Pd(CH2CH2CH2CH2)(SePh)(2)(bpy) (bpy = 2,2 '-bipyridine) and MMe2(SePh)(2)(L-2) (M = Pd, Pt; L-2 = bpy, 1,10-phenanthroline) and C···O and C···E bond formation at palladium(IV); Inorganic Chemistry
Oxidation of Diorganopalladium(II) Complexes by Water and Halogens: Reactions Involving Methyl Group Transfer and Structural Studies of Hydrogen-Bonded Adducts Formed by Aryl Alcohols with the Pallada(IV)cyclopentane Complex Pd(CH2CH2CH2CH2)(OH){(pz)(3)BH}([(pz)(3)BH](-)=tris(pyrazol-1-yl)borate); Organometallics
Oxidation of organometallic complexes by water: Synthesis of diorgano(hydroxo)platinum(IV) complexes and the structure of a diorgano(aqua)platinum(IV) complex of tris(pyridin-2-yl)methanol, [PtPh(2){(py)(3)COH-N,N',N''}(OH2)][NO3](2)·H2O; Journal of Organometallic Chemistry
Oxidation of organometallics by group 16 oxidants (O2CPh)2, (SPh)2 and (SePh)2: synthesis and structures of pallada(IV)cyclic complexes and MMe2(SePh)2(L2) (L2=BPY, PH; XVIIIth International Conference on Organometallic Chemistry
Oxidation reactions using water, hydrogen peroxide and halogens to give pallada(IV)cyclopentane complexes PdX(C4H8){(pz)3BH} (X = OH, Cl, Br, I). The X-ray strucutre of the hydroxoplatinum(IV) complex Pt(OH)Me2{(pz)3BH}, formed using water as an oxidant; Journal of Organometallic Chemistry
Platinum-tin bonded complexes, including a structural analysis of the octahedral tris(pyrazol-1-y) borate complex Pt(SnMe3)Me2{(pz)3BH-N,N',N'}; Australian Journal of Chemistry
SnBrMe3 and dichalcogenides (ER)(2) as oxidants: Synthesis of platinum(IV) complexes, and C···C and C···E coupling from pallada(IV)cyclopentane complexes and PdMe2(EPh){(pz)(3)BH} {E = O2C, S, Se; [(pz)(3)BH](-) tris(pyrazol-1-yl)borate}; Journal of Organometallic Chemistry
Synthesis and carbonylation studies on methylpalladium(II) complexes containing chelating pyridinecarboxylate ligands: dynamic behaviour of the ligands and implications for the carbonylation mechanism; Journal of the Chemical Society - Dalton Transactions
Synthesis and Characterization of Ambient Temperature Stable Organopalladium(IV) Complexes, Including Aryl-, h1-Allyl-, Ethylpalladium(IV) and Pallada(IV)cyclopentane Complexes. Structures of Poly(pyrazol-1-yl)borate Complexes PdMe3{(pz)3BH} and PdMe3{(pz)4B} and Three Polymorphs of PdMe2Et{(pz)3BH}; Organometallics
Synthesis and theoretical studies of a diorganohydridoplatinum(IV) complex, PtHMe(2){(pz)(3)BH-N,N',N''}([(pz)(3)BH](-)=tris(pyrazol-1-yl)borate); Organometallics
Synthesis of Methylpalladium(II) and Platinum(II) Complexes Containing Labile Chelates and Olefinic Tertiary Phosphine Ligands. Intramolecular Insertion of an Olefin into a Pd(II)-Carbon Bond, and Activation of a C-H Bond by a Pt(II) Complex; Journal of the Chemical Society - Dalton Transactions
Synthetic and structural studies of methyl- and phenylpalladium(II) complexes of poly(pyrazol-1-yl)borates, and the h3-allylpalladium(II) complex Pd(h3-C3H5){(pz)3BH-N,N'}; Journal of Organometallic Chemistry
Water and protic acids as oxidants for platinum(II): Diorgano(hydrido)platinum(IV) and diorgano(hydroxo)platinum(IV) chemistry, including structural studies of poly(pyrazol-1-yl)borate complexes Pt(OH)R-2{(pz)(3)BH} (R=methyl, p-tolyl) and Pt(OH)Me-2{(pz)(4)B}·H2O; Organometallics

Research Projects

Research Candidate Supervision